Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst

Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst

Current heterogeneous catalysts lack the fine steric and electronic tuning required for catalyzing the selective dimerization of ethylene to 1-butene, which remains one of the largest industrial processes still catalyzed by homogeneous catalysts. Here, we report that a metal-organic framework catalyzes ethylene dimerization with a combination of activity and selectivity for 1-butene that is pre...

Production of 1-Butene via Selective Ethylene Dimerization by Addition of Bromoethane as a New Promoter to Titanium-Based Catalyst in the Presence of Tetrahydropyran Modifier and Triethylaluminum Co-Catalyst

a comparison of teachers and supervisors, with respect to teacher efficacy and reflection

supervisors play an undeniable role in training teachers, before starting their professional experience by preparing them, at the initial years of their teaching by checking their work within the proper framework, and later on during their teaching by assessing their progress. but surprisingly, exploring their attributes, professional demands, and qualifications has remained a neglected theme i...

[Ti(OC4H9)4/2,5-Dimethoxytetrahydrofuran/ TEA/Ethylene Chlorobromide] as a Novel Homogeneous Catalyst System Effective for the Ethylene Dimerization Reaction

In the present research, the titanium-catalyzed ethylene dimerization and more specifically, the concomitant byproducts and polymer formation have been studied in the presence of 2,5-dimethoxytetrahydrofuran as an electron donor compound in the combination with triethylaluminium (TEA) as activator. Then, we added ethylene chlorobromide as a new efficient promoter to the relevant catalyst system...

Oxidation of Ethylene to Ethylene Oxide by Selenium Modified Silver Catalyst

Oxidation of ethylene to ethylene oxide over silver catalyst and selenium modified catalyst has been studied by continuous flow and pulse techniques over the temperature range of 230-280 °C. The results are discussed in terms of reaction mechanisms proposed by others, rejecting mechanisms which involve peroxide formation. It has been shown that not only selectivity towards ethylene oxide pr...